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Physics practicals class xi, objective of the experiment :, to determine the surface tension of a liquid by capillary rise method..

How do you define surface tension?

Surface tension is the property of a liquid, by virtue of which its free surface at rest behaves like an elastic skin or a stretched rubber membrane, with a tendency to contract so as to occupy minimum surface area. This property is caused by cohesion of molecules and is responsible for much of the behaviors of liquids.

The property of surface tension is revealed, for example, by the ability of some objects to float on the surface of water, even though they are denser than water.  Surface tension is also seen in the ability of some insects, such as water striders, and even reptiles like basilisk, to run on the water’s surface.

surface tension experiment pdf

The Theory Behind Surface Tension

Surface tension has been well- explained by the molecular theory of matter. According to this theory, cohesive forces among liquid molecules are responsible for the phenomenon of surface tension. The molecules well inside the liquid are attracted equally in all directions by the other molecules. The molecules on the surface experience an inward pull.

surface tension experiment pdf

So, a network is formed against the inward pull, in order to move a molecule to the liquid surface.  It results in a greater potential energy on surface molecules. In order to attain minimum potential energy and hence stable equilibrium, the free surface of the liquid tends to have the minimum surface area and thereby it behaves like a stretched membrane.

Surface tension is measured as the force acting normally per unit length on an imaginary line drawn on the free liquid surface at rest. It is represented by the symbol T (or S). It's S.I. The unit is Nm -1  and dimensional formula is M 1 L 0 T -2.

Capillarity in Liquids

When a capillary tube is dipped in a liquid, the liquid level either rises or falls in the capillary tube.  The phenomena of rise or fall of a liquid level in a capillary tube is called capillarity or capillary action.

How do we define the surface tension of a liquid through the capillary rise method?

When a liquid rises in a capillary tube, the weight of the column of the liquid of density ρ inside the tube is supported by the upward force of surface tension acting around the circumference of the points of contact.

Thus, surface tension;

surface tension experiment pdf

Where,  h - height of the liquid column above the liquid meniscus ρ - Density of the liquid r - Inner radius of the capillary tube θ - Angle of contact

Learning Outcomes

  • Students understand the theory of the surface tension of liquids.
  • Students correlate the property of surface tension with different natural phenomena.
  • Students understand the concept of capillarity in liquids.
  • They are able to relate surface tension and capillarity.

Materials required

  • A clean and dry capillary tube
  • A tipped pointer
  • A beaker containing water
  • A travelling microscope
  • Adjustable wooden stand
  • Clamps and stand

To set up the apparatus :

  • Place the adjustable height stand on the table and make its base horizontal by leveling the screws.
  • Fix the capillary tube and the pointer in a cork, and clamp it in a rigid stand so that the capillary tubes and the pointer become vertical.
  • Adjust the height of the vertical stand, so that the capillary tubes dip in the water in an open beaker.
  • Adjust the position of the pointer, such that its tip just touches the water surface.

To find the capillary rise :

  • Find the least count of the travelling microscope for the horizontal and the vertical scale.
  • Make the axis of the microscope horizontal.
  • Adjust the height of the microscope using the height adjusting screw.
  • Bring the microscope in front of the capillary tube and clamp it when the capillary rise becomes visible.
  • Make the horizontal cross wire just touch the central part of the concave meniscus.
  • Note the reading of the position of the microscope on the vertical scale.
  • Now, carefully remove the beaker containing water
  • Move the microscope horizontally and bring it in front of the pointer.
  • Lower the microscope and make the horizontal cross wire touch the tip of the pointer.
  • Corresponding vertical scale readings are noted.
  • The difference in the two readings (i.e., height of water meniscus and height of the tip of pointer) will give the capillary rise of the given liquid.
  • We can repeat the experiment by changing the height of the wooden stand.

To find the internal diameter of the capillary tube :

  • Place the capillary tube horizontally on the adjustable stand.
  • Focus the microscope on the end dipped in water.
  • Make the horizontal cross- wire touch the inner circle at A (fig i). Note microscope reading on the vertical scale.
  • Raise the microscope to make the horizontal cross wire touch the circle at B (fig ii). Note the vertical scale reading.
  • The difference between the two readings will give the vertical internal diameter (AB) of the tube.
  • Move the microscope on the horizontal scale and make the vertical cross wire touch the inner circle at C (fig iii). Note microscope reading on the horizontal scale.
  • Move the microscope to the right to make the vertical cross wire touch the circle at D  (fig iv). Note the horizontal scale reading.
  • The difference between the two readings will give the horizontal internal diameter (CD) of the tube.

surface tension experiment pdf

  • We can calculate the diameter of the tube by calculating the mean of the vertical and horizontal internal diameters. Half of the diameter will give the radius of the capillary tube.

Observations

Least count of the travelling microscope = Value of one MSD / Number of divisions on the Vernier

surface tension experiment pdf

No Radius of the water meniscus Reading at tht tip of pointer Height, h = h -h   (cm)
M.S.R. (cm) V.S.R. (div.) Total = MSR+(VSR×LC)  h  (cm) M.S.R. (cm) V.S.R. (div.) Total = MSR+(VSR×LC)  h  (cm)
1
2
3
4
5

Mean h = ……….......... cm

= ............. ×10 -2  m

Microscope readings for cross wire in position, Internal diameter Internal radius, 
A

(cm)

B

(cm)

C

(cm)

D

(cm)

Vertical, Y= B-A (cm) Horizontal, X=D-C (cm) Mean, 
 

 

Calculations

Density of water at observed temperature, ρ = ............ kgm -3

Angle of contact of water in glass, θ   = 8 o

surface tension experiment pdf

Note the values of  h in the first table and r in the second table for each capillary tube separately  and find the value of T in each case.

Surface tension ,

surface tension experiment pdf

= .................. N/m

Surface tension of water  is ………………… N/m

Viva-Voce [Surface Tension]

Q.1: Define surface tension?

Ans. “The tangential cohesive force acting along the unit length of the surface of a liquid”

Where F = total force along a line

L = length of the line

In this experiment:

F = m g = weight of the pan + weight in the pan.

L = 2 (length of the slide) + 2 (breadth of the slide).

Sometime we neglect the breadth since it is very small.

Q.2: What are units of surface tension in C.G.S. and S.I. (M.K.S.) system?

Ans. Dynes / cm (C.G.S.)

Newton / meter (M.K.S.)

  Q.3: What are cohesion and adhesion force?

Ans. Cohesion force is the attractive force between like molecules, whereas, the adhesion is the

attractive force between unlike molecules, e.g. attraction between glass slide and the liquid.

Q.4: What are the factors affecting the surface tension?

Ans. (a) Nature of liquid (b) Nature of the surface in contact (c) Temperature

 Q.5: What is the effect of temperature on the surface tension?

Ans. Surface tension decreases with the rise of temperature.

Q.6: Define critical temperature.

Ans. The temperature at which the surface tension is zero.

Q.7: Why the free surface of water is concave but that of mercury is convex?

Ans. The free surface of water is concave because:

Cohesion force between water molecules >> adhesion force between water and gas molecules

Because the free surface of mercury is convex because Cohesion force >> adhesion force

Q.8: What is the shape of free surface at critical temperature?

Ans. At critical temperature the surface tension because zero hence the free surface is flat.

Q.9: Why the surface of the slide should not be oily?

Ans. The surface tension will decrease.

Q.10: Define angle of contact ?

Ans. Angle of contact, for a pair of solid and liquid, id define as

“the angle between tangent to the liquid surface drawn at the point of contact and the solid

surface inside the liquid.”

Q.11: Give some practical applications of surface tension.

Ans. (a) A drop of falling liquid is always in spherical shape.

(b) We use oily substances to set out hairs.

(c) We use soaps and detergent for cleaning clothes.

(d) A thin layer of water over the umbrella protects us against light rain.

(e) Capillary action e.g. rising of oil in the wick of a lamp.

(f) Flying insects can walk on water surface without getting their feel wet.

Physics is one of the most important subjects in Class 12. As the CBSE exam approaches, students get busy preparing for different subjects. But an essential part of the  CBSE exam  is the practical exams which consist of 30 marks.

Students must know all the experiments along with theorems, laws, and numerical to understand all the concepts of 12th standard physics in a detailed way. Two experiments (8 + 8 marks) are asked from each section in the practical exam. The experiment records and activities consist of 6 marks, the project has 3 marks and viva on the experiment consist of 5 marks.

COMMENTS

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